13-18 May 2018
Casino Conference Centre
Europe/Prague timezone

Diamond-based detectors for future chemistry experiments with superheavy elements

14 May 2018, 14:45
15m
Red Hall (Casino Conference Centre)

Red Hall

Casino Conference Centre

Verbal Chemistry of Actinide and Trans-actinide Elements TAN 1

Speaker

Mr Benjamin Kraus (Paul Scherrer Institute / University Bern)

Description

Today’s state-of-the-art alpha-decay- and SF-detection systems for artificially produced superheavy elements (SHEs) consist of silicon-based detectors. For recent chemistry experiments with SHEs a thermochromatographic channel comprised of silicon solid-state detectors in a sandwich-like geometry (e.g., Cryo On-Line Detector [COLD], Cryo Online Multidetector for Physics And Chemistry of Transactinides [COMPACT]) have been applied [1-5]. The crucial advantage of this method is that the surface of the detector serves directly as the stationary surface in the chromatographic process. Different detector coverages can be applied, e.g. SiO2, Au, Se. This technique allows for unprecedented detection efficiencies thereby giving access to crucial chemical information. Despite the success of this approach, the silicon-based detector setups can only be used for fairly volatile elements or their compounds with adsorption enthalpies ranging from –ΔHads ≈ 60 to 15 kJ/mol. The limiting factor here is the silicon material itself with its rather low band gap of 1.1 eV. As a result, the upper temperature limit for a reliable spectroscopic performance is encountered at around 40°C[6]. Furthermore, Si-based detectors need to be operated in complete darkness.
Due to its unique properties, diamond is a superior candidate for the replacement of silicon as semiconductor material for radiation detection. Diamond is a wide band gap semiconductor (5.4 eV), which allows diamond-based sensors to be operated theoretically up to 1000 °C, even under intense UV/vis/IR-irradiation [7]. Currently, the upper temperature limit of diamond-based detectors for alpha-spectroscopic measurements is pinpointed at around 200 – 300 °C [6, 8].
The application of diamond detectors is a promising prospect for a long sought after extension of the chromatographic range of detector arrays such as the COLD. Using diamond-based detectors with their before mentioned current temperature threshold, the upper limit of the observable adsorption enthalpy –ΔHads could be nearly doubled in comparison to today’s detectors. In other words, this would give access to elements and compounds with stronger adsorption interactions with the chromatographic surface, such as to the one of Hg on Au. Such advancement is necessary for future chemical investigations of less volatile SHEs using the efficient method of thermochromatography.
Herein, we present a most recent investigation on heated diamond-based sensors aiming at highest possible operation temperatures for alpha-spectroscopic measurements. The prospects of their application in SHE experiments are discussed. Furthermore, we present a design study of a future COLD like detection system employing diamond-based detectors.

References:
[1] Eichler R. et al. Nature 447(7140) 72 (2007)
[2] Eichler R. et al. Angewandte Chemie IE 47(17) 3262 (2008)
[3] Eichler R. et al. RCA 98(3) 133 (2010)
[4] Yakushev A. et al. Inorganic Chemistry 53(3) 1624 (2014)
[5] Even J. et al. Science 345(6203) 1491 (2014)
[6] Steinegger P. et al. NIM A 850 61 (2017)
[7] Steinegger P. Dissertation, DCB, University Bern (2016)
[8] Kumar A. et al. NIM A 858 12 (2017)

Primary author

Mr Benjamin Kraus (Paul Scherrer Institute / University Bern)

Co-authors

Dr Robert Eichler (Paul Scherrer Institute / University Bern) Dr Rugard Dressler (Paul Scherrer Institute) Mr Dominik Herrmann (Paul Scherrer Institute) Dr Patrick Steinegger (Joint Institute for Nuclear Research) Dr Nikolay Aksenov (Joint Institute for Nuclear Research) Prof. Andreas Türler (University Bern) Dr Erich Griesmayer (CIVIDEC Instrumentation GmbH) Dr Christina Weiss (CIVIDEC Instrumentation GmbH)

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