13-18 May 2018
Casino Conference Centre
Europe/Prague timezone

The Micro-Optical Ring Electrode: A Sensor for Multiple Actinide Ions Monitoring

17 May 2018, 17:30
1h 30m
Gallery (Casino Conference Centre)

Gallery

Casino Conference Centre

Reitenbergerova 4/95, Mariánské Lázně, Czech Republic
Poster Chemistry of Nuclear Fuel Cycle, Radiochemical Problems in Nuclear Waste Management Poster NFC

Speaker

Mr Gary Linnett (Lancaster University)

Description

We present on the development of the Micro-Optical Ring Electrode (MORE) for the analysis of trans-uranium elements in aqueous mixtures. The MORE is a photo-electrochemical device based on a ring microelectrode that uses the insulator interior to the ring as a light guide. This single device exploits the unique photophysical and electrochemical properties of multiple analytes present in mixtures to quantify them. Our study aims to develop a protocol for the analysis of ions of uranium, neptunium and plutonium, which are most relevant to the nuclear industry, especially in the areas of decommissioning and fuel-reprocessing, where speedy and safe identification of radioactive contaminants is essential.

The technique offers a number of advantages over traditional methods in the area of radiochemical analysis such as real time monitoring in-situ, reduced radiation dose impact to the analyst as a result of greatly reduced sample handling and preparation, improved analysis times allowing quick decision making and a much reduced cost (e.g. compared to ICP-MS and Scintillation counting).

Here we present results of our study on successfully generating photocurrents from uranium containing solutions, and describe the response of the sensor as a function of wavelength of illumination, concentration of sensitizer and scavenger species, and include a discussion of limits of detection and interference from additional analytes. The effect of the MORE’s surface finish on photocurrents will also be discussed.

Primary authors

Mr Gary Linnett (Lancaster University) Dr Poteau Xavier (Sellafield Sites Ltd)

Co-authors

Dr Fabrice Andrieux (Lancaster University ) Dr Nick Atherton (Sellafield Sites LTD)

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