11–16 May 2014
Casino Conference Centre
Europe/Prague timezone

Solid state diffusion interactions of metallic uranium with technetium

13 May 2014, 14:00
15m
Mirror Hall (Casino Conference Centre)

Mirror Hall

Casino Conference Centre

Reitenbergerova 4/95, Mari&#225;nsk&#233; L&#225;zn&#283;, Czech Republic <font color=white>
Verbal Chemistry of Actinide and Trans-actinide Elements Chemistry of Actinide and Trans-actinide Elements 3

Speaker

Prof. Ken Czerwinski (University of Nevada, Las Vegas, United States)

Description

In metallic nuclear fuels, uranium will interact with fission products formed at higher burn-ups. Understanding the binary interactions between components is helpful in building a description of the overall system consisting of fuel and fission products. Many of the fission product metals are easy to obtain and study in reactions with metallic depleted uranium to simulate conditions in an active metallic nuclear fuel. Technetium is a major fission product (~ 6% from 235-U) and very little is known about its interaction with uranium: only one phase has been identified (i.e., U2Tc) and no Tc-U binary phase diagram is reported. In this study, the interaction between metallic uranium and technetium at elevated temperature has been investigated. Discs of uranium and technetium were prepared into a couple and heat treated at 1023 K for 120 h. After treatment, the couple was analyzed by Electron Microscopy and the U2Tc phase was identified. In order to better understand the physico-chemistry of binary alloys of uranium with transition metals, discs consisting of uranium with molybdenum, rhenium and ruthenium were prepared, heat treated at 1023 K and analyzed by Electron Microscopy.

Primary authors

Dr Daniel Koury (University of Nevada, Las Vegas, United States) Dr Frederic Poineau (University of Nevada, Las Vegas, United States)

Co-authors

Mr Erik Johnstone (University of Nevada, Las Vegas, United States) Prof. Ken Czerwinski (University of Nevada, Las Vegas, United States)

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